Sn (II) Ion- Selective Membrane Electrode based on Dibenzo-18-Crown-6
نویسندگان
چکیده مقاله:
We found that dibenzo-18-crown-6 (DB18C6) can be used as an ionophore to make a tin (II)-ionselectivemembrane electrode. The electrode exhibits a near Nernstian response for Sn2+ ions over aconcentration range from 1.0× 10-6 – 1.0× 10-2 M with a slope of 27.5 ± 0.6 mV per concentration decadein an acidic solution (pH=1). The limit of detection was 8.0× 10-7 M. It has a response time of < 20s andcan be used for at least 3 months without any divergence in potentials. The proposed membrane electroderevealed very good selectivity for Sn2+ ions over a wide variety of other cations and could be used inacidic media. It was used as indicator electrode in potentiometric determination of tin (II) ion in realsample.
منابع مشابه
sn (ii) ion- selective membrane electrode based on dibenzo-18-crown-6
we found that dibenzo-18-crown-6 (db18c6) can be used as an ionophore to make a tin (ii)-ionselectivemembrane electrode. the electrode exhibits a near nernstian response for sn2+ ions over aconcentration range from 1.0× 10-6 – 1.0× 10-2 m with a slope of 27.5 ± 0.6 mv per concentration decadein an acidic solution (ph=1). the limit of detection was 8.0× 10-7 m. it has a response time of < 20s an...
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عنوان ژورنال
دوره 1 شماره 1
صفحات 15- 19
تاریخ انتشار 2004-05-01
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